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Use of ambient ionization high-resolution mass spectrometry for the kinetic analysis of organic surface reactions

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Use of ambient ionization high-resolution mass spectrometry for the kinetic analysis of organic surface reactions

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dc.contributor.author	Sen, Rickdeb
dc.contributor.author	Escorihuela Fuentes, Jorge
dc.contributor.author	Smulders, Maarten M. J.
dc.contributor.author	Zuilhof, Han
dc.date.accessioned	2018-09-04T17:33:54Z
dc.date.available	2018-09-04T17:33:54Z
dc.date.issued	2016
dc.identifier.citation	Sen, Rickdeb Escorihuela Fuentes, Jorge Smulders, Maarten M. J. Zuilhof, Han 2016 Use of ambient ionization high-resolution mass spectrometry for the kinetic analysis of organic surface reactions Langmuir 32 14 3412 3419
dc.identifier.uri	http://hdl.handle.net/10550/67399
dc.description.abstract	In contrast to homogeneous systems, studying the kinetics of organic reactions on solid surfaces remains a difficult task due to the limited availability of appropriate analysis techniques that are general, highthroughput, and capable of offering quantitative, structural surface information. Here, we demonstrate how direct analysis in real time mass spectrometry (DART-MS) complies with above considerations and can be used for determining interfacial kinetic parameters. The presented approach is based on the use of a MS tag that in principle allows application to other reactions. To show the potential of DART-MS, we selected the widely applied strain-promoted alkyne−azide cycloaddition (SPAAC) as a model reaction to elucidate the effects of the nanoenvironment on the interfacial reaction rate.
dc.language.iso	eng
dc.relation.ispartof	Langmuir, 2016, vol. 32, num. 14, p. 3412-3419
dc.subject	Reaccions químiques
dc.subject	Química orgànica
dc.title	Use of ambient ionization high-resolution mass spectrometry for the kinetic analysis of organic surface reactions
dc.type	journal article	es_ES
dc.date.updated	2018-09-04T17:33:55Z
dc.identifier.doi	10.1021/acs.langmuir.6b00427
dc.identifier.idgrec	126742
dc.rights.accessRights	open access	es_ES