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Self-assembly of catalytically-active supramolecular coordination compounds within metal-organic frameworks

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Self-assembly of catalytically-active supramolecular coordination compounds within metal-organic frameworks

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dc.contributor.author	Adam Ortiz, Rosa
dc.contributor.author	Mon Conejero, Marta
dc.contributor.author	Greco, Rossella
dc.contributor.author	Kalinke, Lucas H. G.
dc.contributor.author	Vidal-Moya, Alejandro
dc.contributor.author	Fernandez, Antonio
dc.contributor.author	Winpenny, Richard E. P.
dc.contributor.author	Doménech Carbó, Antonio
dc.contributor.author	Leyva-Pérez, Antonio
dc.contributor.author	Armentano, Donatella
dc.contributor.author	Pardo Marín, Emilio
dc.contributor.author	Ferrando Soria, Jesús
dc.date.accessioned	2019-07-23T08:17:08Z
dc.date.available	2020-06-13T04:45:05Z
dc.date.issued	2019
dc.identifier.citation	Adam Ortiz, Rosa Mon Conejero, Marta Greco, Rossella Kalinke, Lucas H. G. Vidal-Moya, Alejandro Fernandez, Antonio Winpenny, Richard E. P. Doménech Carbó, Antonio Leyva-Pérez, Antonio Armentano, Donatella Pardo Marín, Emilio Ferrando Soria, Jesús 2019 Self-Assembly of Catalytically-Active Supramolecular Coordination Compounds within Metal-Organic Frameworks Journal of the American Chemical Society 141 26 10350 10360
dc.identifier.uri	https://hdl.handle.net/10550/70986
dc.description.abstract	Supramolecular Coordination Compounds (SCCs) represent the power of Coordination Chemistry methodologies to self-assemble discrete architectures with targeted properties. SCCs are generally synthesised in solution, with isolated fully-coordinated metal atoms as structural nodes, thus severely limited as metal-based catalysts. Metal-Organic Frameworks (MOFs) show unique features to act as chemical nanoreactors for the in-situ synthesis and stabilization of otherwise not accessible functional species. Here, we present the self-assembly of PdII SCCs within the confined space of a preformed MOF (SCCs@MOF) and its post-assembly metalation to give a PdII-AuIII supramolecular assembly, crystallography underpinned. These SCCs@MOF catalyse the coupling of boronic acids and/or alkynes, representative multisite metallic-catalysed reactions in which traditional SCCs tend to decompose, and retain its structural integrity as consequence of the synergetic hybridization between SCCs and MOF. These results open new avenues in both the synthesis of novel SCCs and their use on heterogeneous metal-based Supramolecular Catalysis.
dc.language.iso	eng
dc.relation.ispartof	Journal of the American Chemical Society, 2019, vol. 141, num. 26, p. 10350-10360
dc.subject	Química organometàl·lica
dc.title	Self-assembly of catalytically-active supramolecular coordination compounds within metal-organic frameworks
dc.type	journal article	es_ES
dc.date.updated	2019-07-23T08:17:09Z
dc.identifier.doi	10.1021/jacs.9b03914
dc.identifier.idgrec	133390
dc.embargo.terms	1 year
dc.rights.accessRights	open access	es_ES