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Organocatalytic Enantioselective Synthesis of α-Hydroxyketones through a Friedel−Crafts Reaction of Naphthols and Activated Phenols with Aryl- and Alkylglyoxal Hydrates

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Organocatalytic Enantioselective Synthesis of α-Hydroxyketones through a Friedel−Crafts Reaction of Naphthols and Activated Phenols with Aryl- and Alkylglyoxal Hydrates

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dc.contributor.author	Vila Descals, Carlos
dc.contributor.author	Quintero, Lucía
dc.contributor.author	Blay Llinares, Gonzalo
dc.contributor.author	Muñoz, M. Carmen
dc.contributor.author	Pedro, José Ramón
dc.date.accessioned	2020-04-01T11:07:42Z
dc.date.available	2020-04-01T11:07:42Z
dc.date.issued	2016
dc.identifier.citation	Vila Descals, Carlos Quintero, Lucía Blay Llinares, Gonzalo Muñoz, M. Carmen Pedro, José Ramón 2016 Organocatalytic Enantioselective Synthesis of α-Hydroxyketones through a Friedel−Crafts Reaction of Naphthols and Activated Phenols with Aryl- and Alkylglyoxal Hydrates Organic Letters 18 5652 5655
dc.identifier.uri	https://hdl.handle.net/10550/73734
dc.description.abstract	An efficient organocatalytic asymmetric synthesis of α-hydroxyketones has been developed. Quinine-derived thiourea catalyzed the enantioselective Friedel−Crafts alkylation of naphthols and activated phenols with aryl- and alkylglyoxal hydrates, providing the corresponding chiral α-hydroxyketones with high yields (up to 97%) and excellent enantioselectivities (up to 99% ee).
dc.language.iso	eng
dc.relation.ispartof	Organic Letters, 2016, vol. 18, p. 5652-5655
dc.subject	Química orgànica
dc.subject	Reaccions químiques
dc.subject	Catàlisi
dc.title	Organocatalytic Enantioselective Synthesis of α-Hydroxyketones through a Friedel−Crafts Reaction of Naphthols and Activated Phenols with Aryl- and Alkylglyoxal Hydrates
dc.type	journal article	es_ES
dc.date.updated	2020-04-01T11:07:42Z
dc.identifier.doi	10.1021/acs.orglett.6b02893
dc.identifier.idgrec	114376
dc.rights.accessRights	open access	es_ES