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Magnesium Exchanged Zirconium Metal−Organic Frameworks with Improved Detoxification Properties of Nerve Agents

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Magnesium Exchanged Zirconium Metal−Organic Frameworks with Improved Detoxification Properties of Nerve Agents

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dc.contributor.author	Gil-San-Millan, Rodrigo
dc.contributor.author	López Maya, Elena
dc.contributor.author	́Platero-Prats, Ana E.
dc.contributor.author	Torres-Pérez, Virginia
dc.contributor.author	Delgado, Pedro
dc.contributor.author	́Augustyniak, Adam W.
dc.contributor.author	Kim, Min Kun
dc.contributor.author	Lee, Hae Wan
dc.contributor.author	Ryu, Sam Gon
dc.contributor.author	Navarro, Jorge A. R.
dc.date.accessioned	2020-07-24T10:20:24Z
dc.date.available	2020-07-24T10:20:24Z
dc.date.issued	2019
dc.identifier.citation	Gil-San-Millan, Rodrigo López Maya, Elena &#769Platero-Prats, Ana E. Torres-Pérez, Virginia Delgado, Pedro &#769Augustyniak, Adam W. Kim, Min Kun Lee, Hae Wan Ryu, Sam Gon Navarro, Jorge A. R. 2019 Magnesium Exchanged Zirconium Metal−Organic Frameworks with Improved Detoxification Properties of Nerve Agents Journal of the American Chemical Society 141 30 11801 11805
dc.identifier.uri	https://hdl.handle.net/10550/75353
dc.description.abstract	UiO-66, MOF-808 and NU-1000 metal-organic frameworks exhibit a differentiated reactivity toward [Mg(OMe)2(MeOH)2]4 related to their pore accessibility. Microporous UiO-66 remains unchanged while mesoporous MOF-808 and hierarchical micro/mesoporous NU-1000 materials yield doped systems containing exposed MgZr5O2(OH)6 clusters in the mesoporous cavities. This modification is responsible for a remarkable enhancement of the catalytic activity toward the hydrolytic degradation of P-F and P-S bonds of toxic nerve agents, at room temperature, in unbuffered aqueous solutions.
dc.language.iso	eng
dc.relation.ispartof	Journal of the American Chemical Society, 2019, vol. 141, num. 30, p. 11801-11805
dc.subject	Química organometàl·lica
dc.subject	Materials
dc.title	Magnesium Exchanged Zirconium Metal−Organic Frameworks with Improved Detoxification Properties of Nerve Agents
dc.type	journal article	es_ES
dc.date.updated	2020-07-24T10:20:25Z
dc.identifier.doi	10.1021/jacs.9b05571
dc.identifier.idgrec	138024
dc.rights.accessRights	open access	es_ES