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Custom Coordination Environments for Lanthanoids: Tripodal Ligands Achieve Near-Perfect Octahedral Coordination for Two Dysprosium-Based Molecular Nanomagnets

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Custom Coordination Environments for Lanthanoids: Tripodal Ligands Achieve Near-Perfect Octahedral Coordination for Two Dysprosium-Based Molecular Nanomagnets

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dc.contributor.author	Soo Lim, Kwang
dc.contributor.author	Baldoví, José J.
dc.contributor.author	Jiang, ShangDa
dc.contributor.author	Koo, Bong Ho
dc.contributor.author	Kang, Dong Won
dc.contributor.author	Lee, Woo Ram
dc.contributor.author	Koh, Eui Kwan
dc.contributor.author	Gaita Ariño, Alejandro
dc.contributor.author	Coronado Miralles, Eugenio
dc.contributor.author	Slota, Michael
dc.contributor.author	Bogani, Lapo
dc.contributor.author	Hong, Chang Seop
dc.date.accessioned	2021-05-07T08:15:09Z
dc.date.available	2021-05-08T04:45:05Z
dc.date.issued	2017	es_ES
dc.identifier.citation	Kwang Soo Lim, José J. Baldoví, ShangDa Jiang, Bong Ho Koo, Dong Won Kang, Woo Ram Lee, Eui Kwan Koh, Alejandro Gaita-Ariño, Eugenio Coronado, Michael Slota, Lapo Bogani, Chang Seop Hong, Inorg. Chem. 2017, 56, 9, 4911–4917	es_ES
dc.identifier.uri	https://hdl.handle.net/10550/79242
dc.description.abstract	Controlling the coordination sphere of lanthanoid complexes is a challenging critical step toward controlling their relaxation properties. Here we present the synthesis of hexacoordinated dysprosium single-molecule magnets, where tripodal ligands achieve a near-perfect octahedral coordination. We perform a complete experimental and theoretical investigation of their magnetic properties, including a full single-crystal magnetic anisotropy analysis. The combination of electrostatic and crystal-field computational tools (SIMPRE and CONDON codes) allows us to explain the static behavior of these systems in detail.	es_ES
dc.description.abstract	Controlling the coordination sphere of lanthanoid complexes is a challenging critical step toward controlling their relaxation properties. Here we present the synthesis of hexacoordinated dysprosium single-molecule magnets, where tripodal ligands achieve a near-perfect octahedral coordination. We perform a complete experimental and theoretical investigation of their magnetic properties, including a full single-crystal magnetic anisotropy analysis. The combination of electrostatic and crystal-field computational tools (SIMPRE and CONDON codes) allows us to explain the static behavior of these systems in detail.	en_US
dc.language.iso	en	es_ES
dc.title	Custom Coordination Environments for Lanthanoids: Tripodal Ligands Achieve Near-Perfect Octahedral Coordination for Two Dysprosium-Based Molecular Nanomagnets	es_ES
dc.type	journal article	es_ES
dc.subject.unesco	UNESCO::QUÍMICA	es_ES
dc.identifier.doi	10.1021/acs.inorgchem.6b03118	es_ES
dc.identifier.idgrec	117860	es_ES
dc.accrualmethod	-	es_ES
dc.embargo.terms	0 days	es_ES
dc.relation.projectID	NRF-2015R1A2A1A10055658	es_ES
dc.relation.projectID	Grant NRF-2012-0008901	es_ES
dc.relation.projectID	NRF2010-0020209	es_ES
dc.relation.projectID	ERC-CoG-647301 DECRESIM	es_ES
dc.relation.projectID	ERC-StG-338258 OptoQMol	es_ES
dc.relation.projectID	COST Action 15128 MOLSPIN	es_ES
dc.relation.projectID	MAT2014-56143-R	es_ES
dc.relation.projectID	CTQ2014-52758-P	es_ES
dc.relation.projectID	MDM-2015-0538	es_ES
dc.relation.projectID	GVA/Prometeo Programme of excellence	es_ES