NAGIOS: RODERIC FUNCIONANDO

Selective CO2 sorption using a compartmentalized coordination polymers with discrete voids

Repositori DSpace/Manakin

Valencià Castellano

Inici
Investigació
e-prints
23 - Química
Visualitza element

IMPORTANT: Aquest repositori està en una versió antiga des del 3/12/2023. La nova instal.lació está en https://roderic.uv.es/

Selective CO2 sorption using a compartmentalized coordination polymers with discrete voids

Mostra el registre parcial de l'element

dc.contributor.author	Miguel‐Casañ, Eugenia
dc.contributor.author	Andres-Garcia, Eduardo
dc.contributor.author	Calbo Roig, Joaquín
dc.contributor.author	Giménez Marqués, Mónica
dc.contributor.author	Mínguez Espallargas, Guillermo
dc.date.accessioned	2021-07-15T13:16:50Z
dc.date.available	2021-07-15T13:16:50Z
dc.date.issued	2021
dc.identifier.citation	Miguel&#8208Casañ, Eugenia Andres-Garcia, Eduardo Calbo Roig, Joaquín Giménez Marqués, Mónica Mínguez Espallargas, Guillermo 2021 Selective CO2 sorption using a compartmentalized coordination polymers with discrete voids Chemistry-A European Journal 27 14 4653 4659
dc.identifier.uri	https://hdl.handle.net/10550/79952
dc.description.abstract	Carbon capture and storage with porous materials is one of the most promising technologies to minimize CO2 release into the atmosphere. Here, we report a family of compartmentalized coordination polymers (CCPs) capable of capturing gas molecules in a selective manner based on two novel tetrazole-based ligands. Crystal structures have been modelled theoretically under the Density Functional Theory (DFT) revealing the presence of discrete voids of 380 Å3. Single gas adsorption isotherms of N2, CH4 and CO2 have been measured, obtaining a loading capacity of 0.6, 1.7 and 2.2 molecules/void at 10 bar and at 298 K for the best performing material. Moreover, they present excellent selectivity and regenerability for CO2 in mixtures with CH4 and N2 in comparison with other reported materials, as evidenced by dynamic breakthrough gas experiments. These frameworks are therefore great candidates for separation of gas mixtures in the chemical engineering industry.
dc.language.iso	eng
dc.relation.ispartof	Chemistry-A European Journal, 2021, vol. 27, num. 14, p. 4653-4659
dc.subject	Materials
dc.subject	Gasos d'efecte hivernacle
dc.title	Selective CO2 sorption using a compartmentalized coordination polymers with discrete voids
dc.type	journal article	es_ES
dc.date.updated	2021-07-15T13:16:51Z
dc.identifier.doi	10.1002/chem.202004845
dc.identifier.idgrec	147217
dc.rights.accessRights	open access	es_ES