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Ultramicroporous iron-isonicotinate MOFs combining size-exclusion kinetics and thermodynamics for efficient CO2/N2 gas separation

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Ultramicroporous iron-isonicotinate MOFs combining size-exclusion kinetics and thermodynamics for efficient CO2/N2 gas separation

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dc.contributor.author	Abánades Lázaro, Isabel
dc.contributor.author	Mazarakioti, Eleni C
dc.contributor.author	Andres-Garcia, Eduardo
dc.contributor.author	Vieira, Bruno J. C.
dc.contributor.author	Waerenborgh, João C.
dc.contributor.author	Vitórica-Yrezábal, Iñigo J.
dc.contributor.author	Giménez-Marqués, Mónica
dc.contributor.author	Mínguez Espallargas, Guillermo
dc.date.accessioned	2023-03-30T14:03:06Z
dc.date.available	2023-03-30T14:03:06Z
dc.date.issued	2023
dc.identifier.citation	Abánades Lázaro, Isabel Mazarakioti, Eleni C Andres-Garcia, Eduardo Vieira, Bruno J. C. Waerenborgh, João C. Vitórica-Yrezábal, Iñigo J. Giménez-Marqués, Mónica Mínguez Espallargas, Guillermo 2023 Ultramicroporous iron-isonicotinate MOFs combining size-exclusion kinetics and thermodynamics for efficient CO2/N2 gas separation¿ Journal Of Materials Chemistry a 11 5320 5327
dc.identifier.uri	https://hdl.handle.net/10550/85983
dc.description.abstract	Two ultramicroporous 2D and 3D iron-based Metal-Organic Frameworks (MOFs) have been obtained by solvothermal synthesis using different ratios and concentrations of precursors. Their reduced pore space decorated with pendant pyridine from tangling isonicotinic ligands enables the combination of size-exclusion kinetic gas separation, due to their small pores, with thermodynamic separation, resulting from the interaction of the linker with CO2 molecules. This combined separation results in efficient materials for dynamic breakthrough gas separation with virtually infinite CO2/N2 selectivity in a wide operando range and with complete renewability at room temperature and ambient pressure.
dc.language.iso	eng
dc.relation.ispartof	Journal Of Materials Chemistry a, 2023, vol. 11, p. 5320-5327
dc.subject	Química
dc.title	Ultramicroporous iron-isonicotinate MOFs combining size-exclusion kinetics and thermodynamics for efficient CO2/N2 gas separation
dc.type	journal article	es_ES
dc.date.updated	2023-03-30T14:03:07Z
dc.identifier.doi	10.1039/d2ta08934c
dc.identifier.idgrec	157244
dc.rights.accessRights	open access	es_ES