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Imparting structural robustness of metal-organic cages based on oxo-dimolybdenum clusters

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Imparting structural robustness of metal-organic cages based on oxo-dimolybdenum clusters

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dc.contributor.author Delaporte, Solène
dc.contributor.author Abánades Lázaro, Isabel
dc.contributor.author López Cabrelles, Javier
dc.contributor.author Mazarakioti, Eleni C.
dc.contributor.author Chebourou, Sarah
dc.contributor.author Giménez-Marqués, Mónica
dc.contributor.author Mínguez Espallargas, Guillermo
dc.date.accessioned 2023-11-20T14:11:25Z
dc.date.available 2023-11-20T14:11:25Z
dc.date.issued 2023
dc.identifier.uri https://hdl.handle.net/10550/91259
dc.description.abstract A family of robust and stable molybdenum-based metal-organic cages have been obtained based on the [Mo2O2(μ2-O)2]2+ secondary building unit. The resulting cages are decorated with different pyrdine derivatives that impart structural stability, resulting in the structural elucidation of the activated cage with single-crystal diffraction. The chemical robustness of the cage is also demonstrated by the post-synthetic modification of the cage, which allows the exchange of the pyridine derivatives without rupture of the cage.
dc.language.iso eng
dc.relation.ispartof Dalton Transactions, 2023, vol. 52, p. 15682-15687
dc.source Delaporte, Solène, Abánades Lázaro, Isabel, López Cabrelles, Javier, Mazarakioti, Eleni C., Chebourou, Sarah ,Giménez-Marqués, Mónica, Mínguez Espallargas, Guillermo (2023). Imparting structural robustness of metal-organic cages based on oxo-dimolybdenum clusters. Dalton Transactions 52 15682 15687. https://doi.org/10.1039/D3DT02482B
dc.subject química
dc.title Imparting structural robustness of metal-organic cages based on oxo-dimolybdenum clusters
dc.type journal article
dc.date.updated 2023-11-20T14:11:25Z
dc.identifier.doi 10.1039/D3DT02482B
dc.identifier.idgrec 161855
dc.rights.accessRights open access

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