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Enantiocontrol in the intermolecular cyclopropanation reaction catalyzed by dirhodium(II) complexes with ortho-metalated aryl phosphine ligands

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Enantiocontrol in the intermolecular cyclopropanation reaction catalyzed by dirhodium(II) complexes with ortho-metalated aryl phosphine ligands

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dc.contributor.author Barberis, Mario
dc.contributor.author Lahuerta Peña, Pascual
dc.contributor.author Pérez Prieto, Julia
dc.contributor.author Sanau Torrecilla, Mercedes
dc.date.accessioned 2010-07-28T12:03:12Z
dc.date.available 2010-07-28T12:03:12Z
dc.date.issued 2001
dc.identifier.citation BARBERIS, Mario ; Lahuerta Peña, Pascual ; Pérez Prieto, Julia ; Sanau Torrecilla, Mercedes, 2001, Enantiocontrol in the intermolecular cyclopropanation reaction catalyzed by dirhodium(II) complexes with ortho-metalated aryl phosphine ligands, Chemical communications, vol. 2001, p. 439-440 en
dc.identifier.uri http://hdl.handle.net/10550/16719
dc.description.abstract (P) and (M) dirhodium(II) complexes with ortho-metalated aryl phosphines are assessed as chiral catalysts in the enantioselective cyclopropanation of styrenes by ethyl diazoacetate; enantioselectivities up to 91% and up to 87%, respectively, for cis- and trans-2-arylcyclopropanecarboxylates are observed. en
dc.language.iso en en
dc.subject Enantiocontrol ; Intermolecular cyclopropanation ; Catalyst ; Phosphine ligands en
dc.title Enantiocontrol in the intermolecular cyclopropanation reaction catalyzed by dirhodium(II) complexes with ortho-metalated aryl phosphine ligands en
dc.type journal article es_ES
dc.subject.unesco UNESCO::QUÍMICA en
dc.subject.unesco UNESCO::QUÍMICA::Química macromolecular en
dc.identifier.doi 10.1039/b010145c en
dc.identifier.idgrec 004279 en
dc.type.hasVersion VoR es_ES
dc.identifier.url http://www.rsc.org/ej/CC/2001/b010145c.pdf en

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