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Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(II) complexes with bulky ortho-metalated aryl phosphines

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Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(II) complexes with bulky ortho-metalated aryl phosphines

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dc.contributor.author	Estevan Estevan, Francisco
dc.contributor.author	Lahuerta Peña, Pascual
dc.contributor.author	Lloret Fillol, Julio
dc.contributor.author	Sanau Torrecilla, Mercedes
dc.contributor.author	Úbeda Picot, M. Ángeles
dc.contributor.author	Vila Gomez, Jaume Llorenc
dc.date.accessioned	2010-07-30T11:26:33Z
dc.date.available	2010-07-30T11:26:33Z
dc.date.issued	2004
dc.identifier.citation	ESTEVAN ESTEVAN, Francisco ; Lahuerta Peña, Pascual ; Lloret Fillol, Julio ; Sanau Torrecilla, Mercedes ; Ubeda Picot, M Angeles ; Vila Gomez, Jaume Llorenc, 2004, Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(II) complexes with bulky ortho-metalated aryl phosphines, Chemical communications, vol. 2004, p. 2408-2409	en
dc.identifier.uri	http://hdl.handle.net/10550/16768
dc.description.abstract	Enantiomerically pure dirhodium(II) complexes with ortho-metalated p-substituted aryl phosphines have been shown to be enantio- and diastereoselective in the cyclopropanation of styrene by ethyl diazoacetate. Enantioselectivities up to 91% and diastereoselectivities up to 90% are observed for ethyl cis-2-phenylcyclopropanecarboxylate.	en
dc.language.iso	en	en
dc.subject	Intermolecular ; Reaction ; Dirhodium ; Phosphines ; Cyclopropanation	en
dc.title	Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(II) complexes with bulky ortho-metalated aryl phosphines	en
dc.type	journal article	es_ES
dc.subject.unesco	UNESCO::QUÍMICA	en
dc.subject.unesco	UNESCO::QUÍMICA::Química analítica	en
dc.identifier.doi	10.1039/b408856e	en
dc.identifier.idgrec	012363	en
dc.type.hasVersion	VoR	es_ES
dc.identifier.url	http://www.rsc.org/ej/CC/2004/b408856e.pdf	en