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We use a method recently suggested for evaluating the slope of the Isgur-Wise function, at the zero-recoil point, on the lattice. The computations are performed in the quenched approximation to lattice QCD, on a 24(3) x 48 lattice at beta = 6.2, using an O(a)-improved action for the fermions. We have found unexpectedly large finite-volume effects in such a calculation. These volume corrections turned out to be purely geometrical and independent of the dynamics of the system. After the study of these effects on a smaller volume and for different quark masses, we give approximate expressions that account for them. Using these approximations we find xi'(1) = -1.7 (+2)(-2) and xi'(1) = -1.4 (+2)(-1) for the slope of the Isgur-Wise function, for two mesons composed of a heavy quark slightly heavier and lighter, respectively, than the charm quark, and in both cases, a light antiquark whose mass is about that of the strange quark.
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