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Strain-Promoted Cycloaddition of Cyclopropenes with o-Quinones: A Rapid Click Reaction

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Valencià Castellano

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Strain-Promoted Cycloaddition of Cyclopropenes with o-Quinones: A Rapid Click Reaction

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Gahtory, Digvijay; Sen, Rickdeb; Kuzmyn, Andriy R.; Escorihuela Fuentes, Jorge; Zuilhof, Han

Aquest document és un/a article, creat/da en: 2018

Novel click reactions are of continued interest in fields as diverse as bio-conjugation, polymer science and surface chemistry. Qualification as a proper 'click' reaction requires stringent criteria, including fast kinetics and high conversion, to be met. Herein, we report a novel strain-promoted cycloaddition between cyclopropenes and o-quinones in solution and on a surface. We demonstrate the 'click character' of the reaction in solution and on surfaces for both monolayer and polymer brush functionalization.

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