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Approach Matters: The Kinetics of Interfacial Inverse‐Electron Demand Diels-Alder Reactions

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Approach Matters: The Kinetics of Interfacial Inverse‐Electron Demand Diels-Alder Reactions

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dc.contributor.author Sen, Rickdeb
dc.contributor.author Gahtory, Digvijay
dc.contributor.author Escorihuela Fuentes, Jorge
dc.contributor.author Firet, Judith
dc.contributor.author Pujari, Sidharam P.
dc.contributor.author Zuilhof, Han
dc.date.accessioned 2018-09-04T17:23:24Z
dc.date.available 2018-09-04T17:23:24Z
dc.date.issued 2017
dc.identifier.citation Sen, Rickdeb Gahtory, Digvijay Escorihuela Fuentes, Jorge Firet, Judith Pujari, Sidharam P. Zuilhof, Han 2017 Approach Matters: The Kinetics of Interfacial Inverse‐Electron Demand Diels-Alder Reactions Chemistry-A European Journal 23 53 13015 13022
dc.identifier.uri http://hdl.handle.net/10550/67398
dc.description.abstract Rapid and quantitative click functionalization of surfaces remains an interesting challenge in surface chemistry. In this regard, inverse electron demand Diels-Alder (IEDDA) reactions represent a promising metal‐free candidate. Herein, we reveal quantitative surface functionalization within 15 min. Furthermore, we report the comprehensive effects of substrate stereochemistry, surrounding microenvironment and substrate order on the reaction kinetics as obtained by surface‐bound mass spectrometry (DART‐HRMS).
dc.language.iso eng
dc.relation.ispartof Chemistry-A European Journal, 2017, vol. 23, num. 53, p. 13015-13022
dc.subject Reaccions químiques
dc.subject Química orgànica
dc.title Approach Matters: The Kinetics of Interfacial Inverse‐Electron Demand Diels-Alder Reactions
dc.type journal article es_ES
dc.date.updated 2018-09-04T17:23:24Z
dc.identifier.doi 10.1002/chem.201703103
dc.identifier.idgrec 126743
dc.rights.accessRights open access es_ES

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