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Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metal-Organic Framework

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Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metal-Organic Framework

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dc.contributor.author	Souto González, Xosé M.
dc.contributor.author	Romero Pascual, Jorge
dc.contributor.author	Calbo Roig, Joaquín
dc.contributor.author	Vitórica-Yrezábal, Iñigo J.
dc.contributor.author	Zafra, José L.
dc.contributor.author	Casado, Juan
dc.contributor.author	Ortí Guillén, Enrique
dc.contributor.author	Walsh, Aron
dc.contributor.author	Mínguez Espallargas, Guillermo
dc.date.accessioned	2019-01-18T14:50:15Z
dc.date.available	2019-01-18T14:50:15Z
dc.date.issued	2018
dc.identifier.citation	Souto, Manuel Romero Pascual, Jorge Calbo Roig, Joaquín Vitórica-Yrezábal, Iñigo J. Zafra, José L. Casado, Juan Ortí Guillén, Enrique Walsh, Aron Mínguez Espallargas, Guillermo 2018 Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metal-Organic Framework Journal of the American Chemical Society 140 33 10562 10569
dc.identifier.uri	http://hdl.handle.net/10550/68563
dc.description.abstract	'Breathing' metal-organic frameworks (MOFs) which involve changes in their structural and physical properties upon an external stimulus are an interesting class of crystalline materials due to their range of potential applications including chemical sensors. The addition of redox activity opens up a new pathway for multi-functional 'breathing' frameworks. Herein we report the continuous breathing behavior of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, showing a reversible swelling (up to ca. 40% of the volume cell) upon solvent adsorption. Importantly, the planarity of the TTF linkers is influenced by the breathing behavior, directly impacting on their electrochemical properties, thus opening the way for the development of new electrochemical sensors. Quantum chemical calculations and Raman spectroscopy have been used to provide insights into the tunability of the oxidation potential.
dc.language.iso	eng
dc.relation.ispartof	Journal of the American Chemical Society, 2018, vol. 140, num. 33, p. 10562-10569
dc.subject	Reacció d'oxidació-reducció
dc.subject	Química organometàl·lica
dc.title	Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metal-Organic Framework
dc.type	journal article	es_ES
dc.date.updated	2019-01-18T14:50:16Z
dc.identifier.doi	10.1021/jacs.8b05890
dc.identifier.idgrec	126749
dc.rights.accessRights	open access	es_ES