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Two consecutive magneto-structural gas-solid transformations in non-porous molecular materials

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Two consecutive magneto-structural gas-solid transformations in non-porous molecular materials

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dc.contributor.author	Miguel-Donet, Julia
dc.contributor.author	López Cabrelles, Javier
dc.contributor.author	Calvo Galve, Néstor
dc.contributor.author	Coronado Miralles, Eugenio
dc.contributor.author	Mínguez Espallargas, Guillermo
dc.date.accessioned	2019-01-21T14:59:20Z
dc.date.available	2019-07-20T04:45:05Z
dc.date.issued	2018
dc.identifier.citation	Miguel-Donet, Julia López Cabrelles, Javier Calvo Galve, Néstor Coronado Miralles, Eugenio Mínguez Espallargas, Guillermo 2018 Two consecutive magneto-structural gas-solid transformations in non-porous molecular materials Chemistry-A European Journal 24 47 12426 12432
dc.identifier.uri	http://hdl.handle.net/10550/68604
dc.description.abstract	Modification of the magnetic properties in a solid-state material upon external stimulus has attracted much attention in the recent years for their potential applications as switches and sensors. Within the field of coordination polymers, gas sorption studies typically focus on porous solids, with the gas molecules accommodating in the channels. Here we present a 1D non-porous coordination polymer capable of incorporating HCl gas molecules, which not only causes a reordering of its atoms in the solid state but also provokes dramatic changes in the magnetic behaviour. Subsequently, a further solid-gas transformation can occur with the extrusion of HCl gas molecules causing a second structural rearrangement which is also accompanied by modification in the magnetic path between the metal centres. Unequivocal evidence of the two-step magnetostructural transformation is provided by X-ray single-crystal diffraction.
dc.language.iso	eng
dc.relation.ispartof	Chemistry-A European Journal, 2018, vol. 24, num. 47, p. 12426-12432
dc.subject	Materials
dc.subject	Reaccions químiques
dc.title	Two consecutive magneto-structural gas-solid transformations in non-porous molecular materials
dc.type	journal article	es_ES
dc.date.updated	2019-01-21T14:59:20Z
dc.identifier.doi	10.1002/chem.201802510
dc.identifier.idgrec	126766
dc.embargo.terms	6 months
dc.rights.accessRights	open access	es_ES