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Prussian blue@MoS2 layer composites as highly efficient cathodes for sodium- and potassium-ion batteries

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Prussian blue@MoS2 layer composites as highly efficient cathodes for sodium- and potassium-ion batteries

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dc.contributor.author Morant Giner, Marc
dc.contributor.author Sanchis Gual, Roger
dc.contributor.author Romero Pascual, Jorge
dc.contributor.author Alberola Catalán, Antonio
dc.contributor.author García-Cruz, Leticia
dc.contributor.author Agouram, Said
dc.contributor.author Galbiati, Marta
dc.contributor.author Padial, Natalia M.
dc.contributor.author Waerenborgh, João C.
dc.contributor.author Martí Gastaldo, Carlos
dc.contributor.author Tatay Aguilar, Sergio
dc.contributor.author Forment Aliaga, Alicia
dc.contributor.author Coronado Miralles, Eugenio
dc.date.accessioned 2019-11-15T14:39:37Z
dc.date.available 2019-11-15T14:39:37Z
dc.date.issued 2018
dc.identifier.citation Morant Giner, Marc Sanchis Gual, Roger Romero Pascual, Jorge Alberola Catalán, Antonio García-Cruz, Leticia Agouram, Said Galbiati, Marta Padial, Natalia M. Waerenborgh, João C. Martí Gastaldo, Carlos Tatay Aguilar, Sergio Forment Aliaga, Alicia Coronado Miralles, Eugenio 2018 Prussian blue@MoS2 layer composites as highly efficient cathodes for sodium- and potassium-ion batteries Advanced Functional Materials 28 27 1706125-1 1706125-11
dc.identifier.uri https://hdl.handle.net/10550/72215
dc.description.abstract Prussian blue (PB) represents a simple, economical, and eco-friendly system as cathode material for sodium-ion batteries (SIBs). However, structural problems usually worsen its experimental performance thus motivating the search for alternative synthetic strategies and the formation of composites that compensate these deficiencies. Herein, a straightforward approach for the preparation of PB/MoS2-based nanocomposites is presented. MoS2 provides a 2D active support for the homogeneous nucleation of porous PB nanocrystals, which feature superior surface areas than those obtained by other methodologies, giving rise to a compact PB shell covering the full flake. The nanocomposite exhibits an excellent performance as cathode for SIBs with discharge capacity values up to 177 mA h g−1 and a specific capacitance of 354 F g−1. These values are even larger for the intercalation of K+ ions (up to 215 mA h g−1, reaching a specific capacitance of 489 F g−1). Compared to similar composites, superior performance can be ascribed to a synergistic effect of the coordination compound with the 2D material.
dc.language.iso eng
dc.relation.ispartof Advanced Functional Materials, 2018, vol. 28, num. 27, p. 1706125-1-1706125-11
dc.subject Materials compostos
dc.title Prussian blue@MoS2 layer composites as highly efficient cathodes for sodium- and potassium-ion batteries
dc.type journal article es_ES
dc.date.updated 2019-11-15T14:39:38Z
dc.identifier.doi 10.1002/adfm.201706125
dc.identifier.idgrec 122413
dc.rights.accessRights open access es_ES

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