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Enantioselective addition of Et2Zn to seven-membered cyclic imines catalyzed by a (R)-VAPOL-Zn(II) complex

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Enantioselective addition of Et2Zn to seven-membered cyclic imines catalyzed by a (R)-VAPOL-Zn(II) complex

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dc.contributor.author De Munck, Lode
dc.contributor.author Sukowski, Verena
dc.contributor.author Vila Descals, Carlos
dc.contributor.author Pedro, José Ramón
dc.date.accessioned 2020-03-26T11:15:13Z
dc.date.available 2020-03-26T11:15:13Z
dc.date.issued 2017
dc.identifier.citation De Munck, Lode Sukowski, Verena Vila Descals, Carlos Pedro, José Ramón 2017 Enantioselective addition of Et2Zn to seven-membered cyclic imines catalyzed by a (R)-VAPOL-Zn(II) complex Tetrahedron Letters 58 34 3358 3361
dc.identifier.uri https://hdl.handle.net/10550/73667
dc.description.abstract Various substituted dibenzo[b,f][1,4]oxazepines underwent an enantioselective alkylation with Et2Zn catalyzed by a (R)-VAPOL-Zn(II) complex. The corresponding chiral 11-ethyl-10,11-dihydrodibenzo[b,f][1,4]oxazepine derivatives were obtained with good yields and moderate enantioselectivities. This represents the first example of enantioselective addition of Et2Zn to cyclic aldimines.
dc.language.iso eng
dc.relation.ispartof Tetrahedron Letters, 2017, vol. 58, num. 34, p. 3358-3361
dc.subject Química orgànica
dc.subject Catàlisi
dc.title Enantioselective addition of Et2Zn to seven-membered cyclic imines catalyzed by a (R)-VAPOL-Zn(II) complex
dc.type journal article es_ES
dc.date.updated 2020-03-26T11:15:13Z
dc.identifier.doi 10.1016/j.tetlet.2017.07.042
dc.identifier.idgrec 120356
dc.rights.accessRights open access es_ES

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