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Direct catalytic cross-coupling of alkenyllithium compounds

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dc.contributor.author	Hornillos, Valentín
dc.contributor.author	Giannerini, Massimo
dc.contributor.author	Vila Descals, Carlos
dc.contributor.author	Fañanás-Mastral, Martín
dc.contributor.author	Feringa, Ben L.
dc.date.accessioned	2020-03-26T13:13:21Z
dc.date.available	2020-03-26T13:13:21Z
dc.date.issued	2015
dc.identifier.citation	Hornillos, Valentín Giannerini, Massimo Vila Descals, Carlos Fañanás-Mastral, Martín Feringa, Ben L. 2015 Direct catalytic cross-coupling of alkenyllithium compounds Chemical Science 6 2 1394 1398
dc.identifier.uri	https://hdl.handle.net/10550/73675
dc.description.abstract	A catalytic method for the direct cross-coupling of alkenyllithium reagents with aryl and alkenyl halides is described. The use of a catalyst comprising Pd2(dba)3/XPhos allows for the stereoselective preparation of a wide variety of substituted alkenes in high yields under mild conditions. In addition (1-ethoxyvinyl)lithium can be efficiently converted into substituted vinyl ethers which, after hydrolysis, give readily access to the corresponding methyl ketones in a one pot procedure.
dc.language.iso	eng
dc.relation.ispartof	Chemical Science, 2015, vol. 6, num. 2, p. 1394-1398
dc.subject	Catàlisi
dc.subject	Química organometàl·lica
dc.title	Direct catalytic cross-coupling of alkenyllithium compounds
dc.type	journal article	es_ES
dc.date.updated	2020-03-26T13:13:22Z
dc.identifier.doi	10.1039/C4SC03117B
dc.identifier.idgrec	101068
dc.rights.accessRights	open access	es_ES