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A Combination of Visible-Light Organophotoredox Catalysis and Asymmetric Organocatalysis for the Enantioselective Mannich Reaction of Dihydroquinoxalinones with Ketones

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A Combination of Visible-Light Organophotoredox Catalysis and Asymmetric Organocatalysis for the Enantioselective Mannich Reaction of Dihydroquinoxalinones with Ketones

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dc.contributor.author	Rostoll Berenguer, Jaume
dc.contributor.author	Blay Llinares, Gonzalo
dc.contributor.author	Muñoz, M. Carmen
dc.contributor.author	Pedro, José Ramón
dc.contributor.author	Vila Descals, Carlos
dc.date.accessioned	2020-04-02T10:21:35Z
dc.date.available	2020-07-11T04:45:05Z
dc.date.issued	2019
dc.identifier.citation	Rostoll-Berenguer, Jaume Blay Llinares, Gonzalo Muñoz, M. Carmen Pedro, José Ramón Vila Descals, Carlos 2019 A Combination of Visible-Light Organophotoredox Catalysis and Asymmetric Organocatalysis for the Enantioselective Mannich Reaction of Dihydroquinoxalinones with Ketones Organic Letters 21 6011 6015
dc.identifier.uri	https://hdl.handle.net/10550/73762
dc.description.abstract	An enantioselective photooxidative Mannich reaction of dihydroquinoxalinones with ketones by the merger of organophotoredox and asymmetric organocatalysis is described. This protocol features very mild reaction conditions using simple and cheap catalysts (Eosin Y and (S)-Proline) for the synthesis of chiral quinoxaline derivatives with good to high yields (up to 94%) and excellent enantioselectivities (up to 99% ee).
dc.language.iso	eng
dc.relation.ispartof	Organic Letters, 2019, vol. 21, p. 6011-6015
dc.subject	Química orgànica
dc.subject	Reaccions químiques
dc.subject	Catàlisi
dc.title	A Combination of Visible-Light Organophotoredox Catalysis and Asymmetric Organocatalysis for the Enantioselective Mannich Reaction of Dihydroquinoxalinones with Ketones
dc.type	journal article	es_ES
dc.date.updated	2020-04-02T10:21:35Z
dc.identifier.doi	10.1021/acs.orglett.9b02157
dc.identifier.idgrec	133730
dc.embargo.terms	1 year
dc.rights.accessRights	open access	es_ES