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Fe(II) spin crossover complexes of a derivative of 2,6-bis(pyrazol-1-yl)pyridine (1-bpp) functionalized with a carboxylic acid in the 3-pyridyl position

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Fe(II) spin crossover complexes of a derivative of 2,6-bis(pyrazol-1-yl)pyridine (1-bpp) functionalized with a carboxylic acid in the 3-pyridyl position

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dc.contributor.author	García López, Víctor
dc.contributor.author	Palacios-Corella, M.
dc.contributor.author	Clemente León, Miguel
dc.contributor.author	Coronado Miralles, Eugenio
dc.date.accessioned	2020-05-07T10:36:48Z
dc.date.available	2020-05-07T10:36:48Z
dc.date.issued	2019
dc.identifier.citation	García López, Víctor Palacios-Corella, M. Clemente León, Miguel Coronado Miralles, Eugenio 2019 Fe(II) spin crossover complexes of a derivative of 2,6-bis(pyrazol-1-yl)pyridine (1-bpp) functionalized with a carboxylic acid in the 3-pyridyl position Polyhedron 170 95 100
dc.identifier.uri	https://hdl.handle.net/10550/74522
dc.description.abstract	The preparation of a new bis(pyrazol-1-yl)pyridine (1-bpp) derivative functionalized with a carboxylic acid in the 3-pyridyl position, bpp3-COOH ligand is reported together with the structure and spin-crossover (SCO) properties of [FeII(bpp3-COOH)2](ClO4)2·0.5EtOH·0.5H2O (1). Magnetic properties of 1 indicate that LS is favored. Desolvation leads to a gradual and incomplete SCO. Solvated and desolvated compounds show LIESST effect.
dc.language.iso	eng
dc.relation.ispartof	Polyhedron, 2019, vol. 170, p. 95-100
dc.subject	Àcids carboxílics
dc.subject	Compostos de coordinació
dc.title	Fe(II) spin crossover complexes of a derivative of 2,6-bis(pyrazol-1-yl)pyridine (1-bpp) functionalized with a carboxylic acid in the 3-pyridyl position
dc.type	journal article	es_ES
dc.date.updated	2020-05-07T10:36:48Z
dc.identifier.doi	10.1016/j.poly.2019.05.029
dc.identifier.idgrec	134322
dc.rights.accessRights	open access	es_ES