NAGIOS: RODERIC FUNCIONANDO

Sublimable Single Ion Magnets Based on Lanthanoid Quinolinate Complexes: The Role of Intermolecular Interactions on Their Thermal Stability

Repositori DSpace/Manakin

Valencià Castellano

Inici
Investigació
e-prints
23 - Química
Visualitza element

IMPORTANT: Aquest repositori està en una versió antiga des del 3/12/2023. La nova instal.lació está en https://roderic.uv.es/

Sublimable Single Ion Magnets Based on Lanthanoid Quinolinate Complexes: The Role of Intermolecular Interactions on Their Thermal Stability

Mostra el registre parcial de l'element

dc.contributor.author	Cañon-Mancisidor, Walter
dc.contributor.author	Gómez Miralles, Sara
dc.contributor.author	Baldoví, José J.
dc.contributor.author	Mínguez Espallargas, Guillermo
dc.contributor.author	Gaita Ariño, Alejandro
dc.contributor.author	Coronado Miralles, Eugenio
dc.date.accessioned	2020-05-25T09:33:14Z
dc.date.available	2020-05-25T09:33:14Z
dc.date.issued	2018
dc.identifier.citation	Cañon-Mancisidor, Walter Gómez Miralles, Sara Baldoví, José J. Mínguez Espallargas, Guillermo Gaita Ariño, Alejandro Coronado Miralles, Eugenio 2018 Sublimable Single Ion Magnets Based on Lanthanoid Quinolinate Complexes: The Role of Intermolecular Interactions on Their Thermal Stability Inorganic Chemistry 57 14170 14177
dc.identifier.uri	https://hdl.handle.net/10550/74709
dc.description.abstract	We report the design, preparation, and characterization of two families of thermally robust coordination complexes based on lanthanoid quinolinate compounds: [Ln(5,7-Br2q)4]− and [Ln(5,7-ClIq)4]−, where q = 8-hydroquinolinate anion and Ln = DyIII, TbIII, ErIII, and HoIII. The sodium salt of [Dy(5,7-Br2q)4]− decomposes upon sublimation, whereas the sodium salt of [Dy(5,7- ClIq)4]−, which displays subtly different crystalline interactions, is sublimable under gentle conditions. The resulting film presents low roughness with high coverage, and the molecular integrity of the coordination complex is verified through AFM, MALDI-TOF, FT-IR, and microanalysis. Crucially, the single-molecule magnet behavior exhibited by [Dy(5,7-ClIq)4]− in bulk remains detectable by ac magnetometry in the sublimated film.
dc.language.iso	eng
dc.relation.ispartof	Inorganic Chemistry, 2018, vol. 57, p. 14170-14177
dc.subject	Materials
dc.subject	Elements químics
dc.title	Sublimable Single Ion Magnets Based on Lanthanoid Quinolinate Complexes: The Role of Intermolecular Interactions on Their Thermal Stability
dc.type	journal article	es_ES
dc.date.updated	2020-05-25T09:33:15Z
dc.identifier.doi	10.1021/acs.inorgchem.8b02080
dc.identifier.idgrec	128689
dc.rights.accessRights	open access	es_ES