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Red Light-Emitting Electrochemical Cells Employing Pyridazine-Bridged Cationic Diiridium Complexes

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Red Light-Emitting Electrochemical Cells Employing Pyridazine-Bridged Cationic Diiridium Complexes

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dc.contributor.author La Placa, Maria-Grazia
dc.contributor.author Igual-Muñoz, Ana M.
dc.contributor.author Romero Pascual, Jorge
dc.contributor.author Daniels, Ruth E.
dc.contributor.author Kozhevnikov, Valery N.
dc.contributor.author Sessolo, Michele
dc.contributor.author Bolink, Henk
dc.date.accessioned 2020-06-19T08:08:41Z
dc.date.available 2020-06-19T08:08:41Z
dc.date.issued 2019
dc.identifier.citation La Placa, Maria-Grazia Igual-Muñoz, Ana M. Romero Pascual, Jorge Daniels, Ruth E. Kozhevnikov, Valery N. Sessolo, Michele Bolink, Henk 2019 Red Light-Emitting Electrochemical Cells Employing Pyridazine-Bridged Cationic Diiridium Complexes Ecs Journal Of Solid State Science And Technology 8 6 84 87
dc.identifier.uri https://hdl.handle.net/10550/75137
dc.description.abstract A rigid dinuclear Ir(III) complex showing high photoluminescence quantum yield in pure films was successfully used to fabricate light-emitting electrochemical cells with and without ionic liquid additives. The devices showed nearly instantaneous electroluminescence after biasing and maximum quantum yield approaching 1%. The lifetime of the devices was found to be limited to approximately 20 hours, which we correlated with the irreversible oxidation of the complex as seen from electrochemical measurements. This work validates the use of highly luminescent dinuclear iridium complexes in light-emitting electrochemical cells. Future studies will pursue materials with more efficient photoluminescence as well as improved electrochemical stability.
dc.language.iso eng
dc.relation.ispartof Ecs Journal Of Solid State Science And Technology, 2019, vol. 8, num. 6, p. 84-87
dc.subject Electroquímica
dc.subject Materials
dc.title Red Light-Emitting Electrochemical Cells Employing Pyridazine-Bridged Cationic Diiridium Complexes
dc.type journal article es_ES
dc.date.updated 2020-06-19T08:08:41Z
dc.identifier.doi 10.1149/2.0161906jss
dc.identifier.idgrec 135959
dc.rights.accessRights open access es_ES

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