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dc.contributor.author | Espinosa López, Miguel | |
dc.contributor.author | Herrera, Jorge | |
dc.contributor.author | Blay Llinares, Gonzalo | |
dc.contributor.author | Cardona Prósper, María Luz | |
dc.contributor.author | Muñoz, M. Carmen | |
dc.contributor.author | Pedro, José Ramón | |
dc.date.accessioned | 2020-09-29T13:54:58Z | |
dc.date.available | 2020-09-29T13:54:58Z | |
dc.date.issued | 2017 | |
dc.identifier.citation | Espinosa López, Miguel Herrera, Jorge Blay Llinares, Gonzalo Cardona Prósper, María Luz Muñoz, M. Carmen Pedro, José Ramón 2017 Copper-catalysed enantioselective Michael addition of malonic esters to β-trifluoromethyl-α,β-unsaturated imines Organic & Biomolecular Chemistry 15 3849 3853 | |
dc.identifier.uri | https://hdl.handle.net/10550/75683 | |
dc.description.abstract | Copper triflate-BOX complexes catalyse the enantioselective conjugate addition of methyl malonate to β-trifluoromethyl-α,β-unsaturated imines to give the corresponding enamines bearing a trifluoromethylated stereogenic centre with good yields, and diastereo- and enantioselectivities. The usefulness of the method has been shown with the synthesis of optically active β-trifluoromethyl δ-amino esters and optically active trifluoromethylpiperidones. | |
dc.language.iso | eng | |
dc.relation.ispartof | Organic & Biomolecular Chemistry, 2017, vol. 15, p. 3849-3853 | |
dc.subject | Química orgànica | |
dc.subject | Catàlisi | |
dc.title | Copper-catalysed enantioselective Michael addition of malonic esters to β-trifluoromethyl-α,β-unsaturated imines | |
dc.type | journal article | es_ES |
dc.date.updated | 2020-09-29T13:54:58Z | |
dc.identifier.doi | 10.1039/C7OB00595D | |
dc.identifier.idgrec | 117521 | |
dc.rights.accessRights | open access | es_ES |