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Thermogalvanic effects on the corrosion of copper in heavy brine LiBr solutions

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Thermogalvanic effects on the corrosion of copper in heavy brine LiBr solutions

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dc.contributor.author Fernández Domene, Ramón Manuel
dc.contributor.author Blasco-Tamarit, E.
dc.contributor.author García-García, D.M.
dc.contributor.author Garcia-Anton, Jose
dc.date.accessioned 2020-12-30T08:17:49Z
dc.date.available 2020-12-30T08:17:49Z
dc.date.issued 2012
dc.identifier.citation Fernández Domene, Ramón Manuel Blasco-Tamarit, E. García-García, D.M. Garcia-Anton, Jose 2012 Thermogalvanic effects on the corrosion of copper in heavy brine LiBr solutions Corrosion Science 63 304 315
dc.identifier.uri https://hdl.handle.net/10550/76832
dc.description.abstract Thermogalvanic corrosion of copper in heavy brine LiBr solutions has been investigated using a zero-resistance ammeter (ZRA). The temperature gradients between copper electrodes immersed in the same LiBr solution result in the formation of thermogalvanic cells with hot anodes, leading to high and sustained thermogalvanic currents. Copper loss rates, calculated using Faraday's law, substantially exceed 0.025 mm year−1, a value regarded as the threshold of low corrosion rates. The effects of thermogalvanic coupling on the surface properties of the anode and the cathode have been analysed by means of electrochemical impedance spectroscopy (EIS). The results obtained in this analysis have been related to the process of copper electrodissolution in bromide media.
dc.language.iso eng
dc.relation.ispartof Corrosion Science, 2012, vol. 63, p. 304-315
dc.subject Electroquímica
dc.title Thermogalvanic effects on the corrosion of copper in heavy brine LiBr solutions
dc.type journal article es_ES
dc.date.updated 2020-12-30T08:17:50Z
dc.identifier.doi 10.1016/j.corsci.2012.06.012
dc.identifier.idgrec 140749
dc.rights.accessRights open access es_ES

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