NAGIOS: RODERIC FUNCIONANDO

Charge-transfer interactions between fullerenes and a mesoporous tetrathiafulvalene-based metal-organic framework

Repositori DSpace/Manakin

Valencià Castellano

Inici
Investigació
e-prints
23 - Química
Visualitza element

IMPORTANT: Aquest repositori està en una versió antiga des del 3/12/2023. La nova instal.lació está en https://roderic.uv.es/

Charge-transfer interactions between fullerenes and a mesoporous tetrathiafulvalene-based metal-organic framework

Mostra el registre parcial de l'element

dc.contributor.author	Souto, Manuel
dc.contributor.author	Calbo Roig, Joaquín
dc.contributor.author	Mañas Valero, Samuel
dc.contributor.author	Walsh, Aron
dc.contributor.author	Mínguez Espallargas, Guillermo
dc.date.accessioned	2021-07-13T13:47:44Z
dc.date.available	2021-07-13T13:47:44Z
dc.date.issued	2019
dc.identifier.citation	Souto, Manuel Calbo Roig, Joaquín Mañas Valero, Samuel Walsh, Aron Mínguez Espallargas, Guillermo 2019 Charge-transfer interactions between fullerenes and a mesoporous tetrathiafulvalene-based metal-organic framework Beilstein Journal Of Nanotechnology 10 1883 1893
dc.identifier.uri	https://hdl.handle.net/10550/79914
dc.description.abstract	The design of metal-organic frameworks (MOFs) incorporating electroactive guest molecules in the pores has become a subject of great interest in order to obtain additional electrical functionalities within the framework while maintaining porosity. Understanding the charge-transfer (CT) process between the framework and the guest molecules is a crucial step towards the design of new electroactive MOFs. Herein, we present the encapsulation of fullerenes (C60) in a mesoporous tetrathiafulvalene (TTF)-based MOF. The CT process between the electron-acceptor C60 guest and the electron-donor TTF ligand is studied in detail by means of different spectroscopic techniques and density functional theory (DFT) calculations. Importantly, gas sorption measurements demonstrate that sorption capacity is maintained after encapsulation of fullerenes, whereas the electrical conductivity is increased by two orders of magnitude due to the CT interactions between C60 and the TTF-based framework.
dc.language.iso	eng
dc.relation.ispartof	Beilstein Journal Of Nanotechnology, 2019, vol. 10, p. 1883-1893
dc.subject	Materials
dc.subject	Nanotecnologia
dc.title	Charge-transfer interactions between fullerenes and a mesoporous tetrathiafulvalene-based metal-organic framework
dc.type	journal article	es_ES
dc.date.updated	2021-07-13T13:47:45Z
dc.identifier.doi	10.3762/bjnano.10.183
dc.identifier.idgrec	134271
dc.rights.accessRights	open access	es_ES