NAGIOS: RODERIC FUNCIONANDO

Electronic, Structural and Functional Versatility in Tetrathiafulvalene-Lanthanide Metal-Organic Frameworks

Repositori DSpace/Manakin

Valencià Castellano

Inici
Investigació
e-prints
23 - Química
Visualitza element

IMPORTANT: Aquest repositori està en una versió antiga des del 3/12/2023. La nova instal.lació está en https://roderic.uv.es/

Electronic, Structural and Functional Versatility in Tetrathiafulvalene-Lanthanide Metal-Organic Frameworks

Mostra el registre parcial de l'element

dc.contributor.author	Castells-Gil, Javier
dc.contributor.author	Mañas Valero, Samuel
dc.contributor.author	Vitórica-Yrezábal, Iñigo J.
dc.contributor.author	Ananias, Duarte
dc.contributor.author	Rocha, João
dc.contributor.author	Santiago, Raúl
dc.contributor.author	Bromley, Stefan T.
dc.contributor.author	Baldoví, José J.
dc.contributor.author	Coronado Miralles, Eugenio
dc.contributor.author	Souto, Manuel
dc.contributor.author	Mínguez Espallargas, Guillermo
dc.date.accessioned	2021-07-13T14:42:46Z
dc.date.available	2021-07-13T14:42:46Z
dc.date.issued	2019
dc.identifier.citation	Castells-Gil, Javier Mañas Valero, Samuel Vitórica-Yrezábal, Iñigo J. Ananias, Duarte Rocha, João Santiago, Raúl Bromley, Stefan T. Baldoví, José J. Coronado Miralles, Eugenio Souto, Manuel Mínguez Espallargas, Guillermo 2019 Electronic, Structural and Functional Versatility in Tetrathiafulvalene-Lanthanide Metal-Organic Frameworks Chemistry-A European Journal 25 12636 12643
dc.identifier.uri	https://hdl.handle.net/10550/79915
dc.description.abstract	Tetrathiafulvalene-lanthanide (TTF-Ln) metal-organic frameworks (MOFs) are an interesting class of multifunctional materials in which porosity can be combined with electronic properties such as electrical conductivity, redox activity, luminescence and magnetism. Herein a new family of isostructural TTF-Ln MOFs is reported, denoted as MUV-5(Ln) (Ln=Gd, Tb, Dy, Ho, Er), exhibiting semiconducting properties as a consequence of the short intermolecular S⋅⋅⋅S contacts established along the chain direction between partially oxidised TTF moieties. In addition, this family shows photoluminescence properties and single-molecule magnetic behaviour, finding near-infrared (NIR) photoluminescence in the Yb/Er derivative and slow relaxation of the magnetisation in the Dy and Er derivatives. As such properties are dependent on the electronic structure of the lanthanide ion, the immense structural, electronic and functional versatility of this class of materials is emphasised.
dc.language.iso	eng
dc.relation.ispartof	Chemistry-A European Journal, 2019, vol. 25, p. 12636 -12643
dc.subject	Materials
dc.subject	Conductivitat elèctrica
dc.title	Electronic, Structural and Functional Versatility in Tetrathiafulvalene-Lanthanide Metal-Organic Frameworks
dc.type	journal article	es_ES
dc.date.updated	2021-07-13T14:42:46Z
dc.identifier.doi	10.1002/chem.201902855
dc.identifier.idgrec	136738
dc.rights.accessRights	open access	es_ES