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Covalent and non-covalent chemistry of 2D black phosphorus

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Covalent and non-covalent chemistry of 2D black phosphorus

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dc.contributor.author Mitrovic, Aleksandra
dc.contributor.author Abellán Sáez, Gonzalo
dc.contributor.author Hirsch, Andreas
dc.date.accessioned 2021-11-09T13:44:41Z
dc.date.available 2021-11-09T13:44:41Z
dc.date.issued 2021
dc.identifier.citation Mitrovic, Aleksandra Abellán Sáez, Gonzalo Hirsch, Andreas 2021 Covalent and non-covalent chemistry of 2D black phosphorus Rsc Advances 11 26093 26101
dc.identifier.uri https://hdl.handle.net/10550/80686
dc.description.abstract The post-graphene era is undoubtedly marked by two-dimensional (2D) sheet polymers, such as black phosphorus (BP). This emerging material has a fascinating structure and outstanding electronic properties and has been postulated for a plethora of applications. The need to circumvent the pronounced oxophilicity of P atoms has dominated the research on this material in recent years, with the objective of finding the most effective method to improve its environmental stability. When it comes to chemical functionalization, the few approaches reported so far involve some drawbacks such as low degree of addition and low production ability. This review presents the concepts and strategies of our studies on the chemical functionalization of BP, both non-covalent and covalent, emphazising the current synthetic challenges. Moreover, we also provide some effective pathways for the chemical activation of the unreactive basal plane, the identification of the effective binding strategies, and the concept to overcome hurdles associated with characterization tools. This work will provide fundamental insights into the controlled chemical functionalization and characterization of BP, fostering the research on this appealing 2D material.
dc.language.iso eng
dc.relation.ispartof Rsc Advances, 2021, vol. 11, p. 26093-26101
dc.subject Materials
dc.subject Química
dc.title Covalent and non-covalent chemistry of 2D black phosphorus
dc.type journal article es_ES
dc.date.updated 2021-11-09T13:44:41Z
dc.identifier.doi 10.1039/D1RA04416H
dc.identifier.idgrec 148911
dc.rights.accessRights open access es_ES

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