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Ruddlesden-Popper hybrid lead bromide perovskite nanosheets of phase pure n = 2: stabilized colloids stored in the solid state

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Ruddlesden-Popper hybrid lead bromide perovskite nanosheets of phase pure n = 2: stabilized colloids stored in the solid state

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dc.contributor.author Cevallos-Toledo, Rita B.
dc.contributor.author Rosa-Pardo, Ignacio
dc.contributor.author Arenal, Raúl
dc.contributor.author Oestreicher, Víctor
dc.contributor.author Fickert, Michael
dc.contributor.author Abellán Sáez, Gonzalo
dc.contributor.author Galian, Raquel Eugenia
dc.contributor.author Pérez Prieto, Julia
dc.date.accessioned 2021-11-16T14:36:38Z
dc.date.available 2021-11-16T14:36:38Z
dc.date.issued 2021
dc.identifier.citation Cevallos-Toledo, Rita B. Rosa-Pardo, Ignacio Arenal, Raúl Oestreicher, Víctor Fickert, Michael Abellán Sáez, Gonzalo Galian, Raquel Eugenia Pérez Prieto, Julia 2021 Ruddlesden-Popper hybrid lead bromide perovskite nanosheets of phase pure n = 2: stabilized colloids stored in the solid state Angewandte Chemie, vol 60, n. 52, pp 27312-27317.
dc.identifier.uri https://hdl.handle.net/10550/80751
dc.description.abstract Ruddlesden-Popper lead halide perovskite (RP-LHP) nano-nanostructures can be regarded as self-assembled quantum wells or superlattices of 3D perovskites with an intrinsic quantum well thickness of a single or a few (n=2-4) lead halide layers; the quantum wells are separated by organic layers. They can be scaled down to a single quantum well dimension. Here, the preparation of highly (photo)chemical and colloidal stable hybrid LHP nanosheets (NSs) of ca. 7.4 μm lateral size and 2.5 nm quantum well height (thereby presenting a deep blue emission at ca. 440 nm), is reported for the first time. The NSs are close-lying and they even interconnect when deposited on a substrate. Their synthesis is based on the use of the p-toluenesulfonic acid/dodecylamine (pTS/DDA) ligand pair and their (photo)chemical stability and photoluminescence is enhanced by adding EuBr2 nanodots (EuNDs). Strikingly, they can be preserved as a solid and stored for at least one year. The blue emissive colloid can be recovered from the solid as needed by simply dispersing the powder in toluene and then using it to prepare solid films, making them very promising candidates for manufacturing devices.
dc.language.iso eng
dc.relation.ispartof Angewandte Chemie, 2021
dc.subject Col·loides
dc.subject Nanoestructures
dc.title Ruddlesden-Popper hybrid lead bromide perovskite nanosheets of phase pure n = 2: stabilized colloids stored in the solid state
dc.type journal article es_ES
dc.date.updated 2021-11-16T14:36:39Z
dc.identifier.doi 10.1002/anie.202113451
dc.identifier.idgrec 148906
dc.rights.accessRights open access es_ES

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