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Asymmetric Addition and Cycloaddition Reactions with Ylidene-Five-Membered Heterocycles

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Asymmetric Addition and Cycloaddition Reactions with Ylidene-Five-Membered Heterocycles

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dc.contributor.author	Torán, Ricardo
dc.contributor.author	Miguélez, Rubén
dc.contributor.author	Sanz Marco, Amparo
dc.contributor.author	Vila Descals, Carlos
dc.contributor.author	Pedro, José Ramón
dc.contributor.author	Blay Llinares, Gonzalo
dc.date.accessioned	2021-12-09T14:59:28Z
dc.date.available	2021-12-09T14:59:28Z
dc.date.issued	2021
dc.identifier.citation	Torán, Ricardo Miguélez, Rubén Sanz Marco, Amparo Vila Descals, Carlos Pedro, José Ramón Blay Llinares, Gonzalo 2021 Asymmetric Addition and Cycloaddition Reactions with Ylidene-Five-Membered Heterocycles Advanced Synthesis & Catalysis 363 23 5196 5234
dc.identifier.uri	https://hdl.handle.net/10550/80961
dc.description.abstract	Five-membered heterocycles bearing an exocyclic double bond have been successfully used as substrates in asymmetric addition and cycloaddition reactions. Ylidene-heterocycles are attractive substrates due to their high functionalization and the presence of an electrophilic conjugated exocyclic double bound that can participate in nucleophilic addition reactions as well as cycloaddition reactions, which may be triggered by the formation of aromatic intermediates or products in many cases. During the last decades, catalytic methodologies have been developed using ylidene-heterocycles as substrates in order to synthesize useful optically active heterocyclic derivatives. 4-Ylidene-pyrazol-5-ones, isoxazolin-5-ones, 2,3-dioxopyrrolidines, rhodanines, oxazolidindiones, Erlenmeyer-Ploch azlactones and 5-ylidene-thiazolones have been successfully used as substrates in asymmetric reactions. This review collects the powerful research in asymmetric addition and cycloaddition reactions where ylidene-five-membered heterocycles have been used.
dc.language.iso	eng
dc.relation.ispartof	Advanced Synthesis & Catalysis, 2021, vol. 363, num. 23, p. 5196-5234
dc.subject	Catàlisi
dc.subject	Reaccions químiques
dc.title	Asymmetric Addition and Cycloaddition Reactions with Ylidene-Five-Membered Heterocycles
dc.type	journal article	es_ES
dc.date.updated	2021-12-09T14:59:31Z
dc.identifier.doi	10.1002/adsc.202100979
dc.identifier.idgrec	149276
dc.rights.accessRights	open access	es_ES