Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolium MOF: Incorporation of POMs and [AuCl4]−
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López Cabrelles, Javier; Mínguez Espallargas, Guillermo; Coronado Miralles, Eugenio
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Aquest document és un/a article, creat/da en: 2016
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The encapsulation of functional molecules inside porous coordination polymers (also known as metal-organic frameworks, MOFs) has become of great interest in recent years at the field of multifunctional materials. In this article, we present a study of the effects of size and charge in the anion exchange process of a Gd based MOF, involving molecular species like polyoxometalates (POMs), and [AuCl4]−. This post-synthetic modification has been characterized by IR, EDAX, and single crystal diffraction, which have provided unequivocal evidence of the location of the anion molecules in the framework. |
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