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Rationalising the Multivariate Modulation of MUV-10 for the Defect-Introduction of Multiple Functionalised Modulators
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Rationalising the Multivariate Modulation of MUV-10 for the Defect-Introduction of Multiple Functionalised Modulators
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| dc.contributor.author | Abánades Lázaro, Isabel | |
| dc.date.accessioned | 2022-04-12T09:34:05Z | |
| dc.date.available | 2023-04-05T04:45:05Z | |
| dc.date.issued | 2022 | |
| dc.identifier.citation | Abánades Lázaro, Isabel 2022 Rationalising the Multivariate Modulation of MUV-10 for the Defect-Introduction of Multiple Functionalised Modulators Journal Of Materials Chemistry a | |
| dc.identifier.uri | https://hdl.handle.net/10550/82301 | |
| dc.description.abstract | Among multivariate Metal-Organic Frameworks, multivariate modulated (MTVM) MOFs offer the possibility of introducing multiple functionalised units into the MOFs as defect-compensating ligands promoting porosity among other defect-related properties. However, there are no studies that rationalise the incorporation of multiple functionalised modulators and their resultant properties, hindering their molecular design and multi-applicability. In this manuscript, we introduce up to five functionalised modulators bearing NO2, F, tBu, OH and NH2 units in significant quantities (up to ca. 31 mol%) into the Ti heterometallic MOF MUV-10 in one-pot synthesis, increasing the porosity up to ca. 1.3-fold in comparison with the pristine material. We have rationalised the incorporation ratios of the different combinations of modulators among other properties. As a proof-of-concept, we have shown that there is up to a 1.7-fold enhancement in the catalytic activity of MTVM MOFs for the regioselective opening of epoxides, anticipating that this protocol can be used to produce multi-functionalised materials with a wide range of applications. | |
| dc.relation.ispartof | Journal Of Materials Chemistry a, 2022 | |
| dc.subject | Química | |
| dc.title | Rationalising the Multivariate Modulation of MUV-10 for the Defect-Introduction of Multiple Functionalised Modulators | |
| dc.type | journal article | es_ES |
| dc.date.updated | 2022-04-12T09:34:06Z | |
| dc.identifier.doi | 10.1039/D2TA00603K | |
| dc.identifier.idgrec | 151202 | |
| dc.embargo.terms | 1 year | |
| dc.rights.accessRights | open access | es_ES |
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