NAGIOS: RODERIC FUNCIONANDO

Synthesis, Structures, and Solution Studies of a New Class of [Mo2O2S2]-Based Thiosemicarbazone Coordination Complexes

Repositori DSpace/Manakin

Valencià Castellano

Inici
Investigació
e-prints
23 - Química
Visualitza element

IMPORTANT: Aquest repositori està en una versió antiga des del 3/12/2023. La nova instal.lació está en https://roderic.uv.es/

Synthesis, Structures, and Solution Studies of a New Class of [Mo2O2S2]-Based Thiosemicarbazone Coordination Complexes

Mostra el registre parcial de l'element

dc.contributor.author	Fuior, Arcadie
dc.contributor.author	Cebotari, Diana
dc.contributor.author	Haouas, Mohamed
dc.contributor.author	Marrot, J.
dc.contributor.author	Mínguez Espallargas, Guillermo
dc.contributor.author	Guérineau, Vincent
dc.contributor.author	Touboul, David
dc.contributor.author	Rusnac, Roman V.
dc.contributor.author	Gulea, Aurelian
dc.contributor.author	Floquet, Sébastien
dc.date.accessioned	2022-07-15T13:01:13Z
dc.date.available	2022-07-15T13:01:13Z
dc.date.issued	2022
dc.identifier.citation	Fuior, Arcadie Cebotari, Diana Haouas, Mohamed Marrot, J. Mínguez Espallargas, Guillermo Guérineau, Vincent Touboul, David Rusnac, Roman V. Gulea, Aurelian Floquet, Sébastien 2022 Synthesis, Structures, and Solution Studies of a New Class of [Mo2O2S2]-Based Thiosemicarbazone Coordination Complexes Acs Omega 7 19 16547 16560
dc.identifier.uri	https://hdl.handle.net/10550/83447
dc.description.abstract	This paper deals with the synthesis, structural studies, and behavior in solution of unprecedented coordination complexes built by the association of a panel of 14 representative thiosemicarbazone ligands with the cluster [Mo2O2S2]2+. These complexes have been thoroughly characterized both in the solid state and in solution by XRD and by NMR, respectively. In particular, HMBC 1H{15N} and 1H DOSY NMR experiments bring important elements for understanding the complexes' behavior in solution. These studies demonstrate that playing on the nature and the position of various substituents on the ligands strongly influences the coordination modes of the ligands as well as the numbers of isomers in solution, mainly 2 products for the majority of complexes and up to 5 for some of them.
dc.language.iso	eng
dc.relation.ispartof	Acs Omega, 2022, vol. 7, num. 19, p. 16547-16560
dc.subject	Química
dc.subject	Compostos de coordinació
dc.title	Synthesis, Structures, and Solution Studies of a New Class of [Mo2O2S2]-Based Thiosemicarbazone Coordination Complexes
dc.type	journal article	es_ES
dc.date.updated	2022-07-15T13:01:13Z
dc.identifier.doi	10.1021/acsomega.2c00705
dc.identifier.idgrec	154350
dc.rights.accessRights	open access	es_ES