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Strain Switching in van der Waals Heterostructures Triggered by a Spin-Crossover Metal-Organic Framework

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Strain Switching in van der Waals Heterostructures Triggered by a Spin-Crossover Metal-Organic Framework

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dc.contributor.author Boix Constant, Carla
dc.contributor.author García López, Víctor
dc.contributor.author Navarro Moratalla, Efrén
dc.contributor.author Clemente León, Miguel
dc.contributor.author Zafra, José L.
dc.contributor.author Casado, Juan
dc.contributor.author Guinea, F.
dc.contributor.author Mañas Valero, Samuel
dc.contributor.author Coronado Miralles, Eugenio
dc.date.accessioned 2023-01-18T13:57:31Z
dc.date.available 2023-01-18T13:57:31Z
dc.date.issued 2022
dc.identifier.citation Boix Constant, Carla García López, Víctor Navarro Moratalla, Efrén Clemente León, Miguel Zafra, José L. Casado, Juan Guinea, F. Mañas Valero, Samuel Coronado Miralles, Eugenio 2022 Strain Switching in van der Waals Heterostructures Triggered by a Spin-Crossover Metal-Organic Framework Advanced Materials 34 11 2110027
dc.identifier.uri https://hdl.handle.net/10550/85015
dc.description.abstract Van der Waals heterostructures (vdWHs) provide the possibility of engineering new materials with emergent functionalities that are not accessible in another way. These heterostructures are formed by assembling layers of different materials used as building blocks. Beyond inorganic 2D crystals, layered molecular materials remain still rather unexplored, with only few examples regarding their isolation as atomically thin layers. Here, the family of van der Waals heterostructures is enlarged by introducing a molecular building block able to produce strain: the so-called spin-crossover (SCO). In these metal-organic materials, a spin transition can be induced by applying external stimuli like light, temperature, pressure, or an electric field. In particular, smart vdWHs are prepared in which the electronic and optical properties of the 2D material (graphene and WSe2) are clearly switched by the strain concomitant to the spin transition. These molecular/inorganic vdWHs represent the deterministic incorporation of bistable molecular layers with other 2D crystals of interest in the emergent fields of straintronics and band engineering in low-dimensional materials.
dc.language.iso eng
dc.relation.ispartof Advanced Materials, 2022, vol. 34, num. 11, p. 2110027
dc.subject Materials
dc.title Strain Switching in van der Waals Heterostructures Triggered by a Spin-Crossover Metal-Organic Framework
dc.type journal article es_ES
dc.date.updated 2023-01-18T13:57:32Z
dc.identifier.doi 10.1002/adma.202110027
dc.identifier.idgrec 150427
dc.rights.accessRights open access es_ES

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