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Description of Solid-to-Solid Redox Processes Based on the Voltammetry of Immobilized Particles Methodology: A Logistic Approximation

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Description of Solid-to-Solid Redox Processes Based on the Voltammetry of Immobilized Particles Methodology: A Logistic Approximation

dc.contributor.author	Doménech Carbó, Antonio
dc.date.accessioned	2023-06-15T07:49:34Z
dc.date.available	2023-06-16T04:45:06Z
dc.date.issued	2022	es_ES
dc.identifier.citation	Doménech-Carbó, A. (2022). Description of Solid-to-Solid Redox Processes Based on the Voltammetry of Immobilized Particles Methodology: A Logistic Approximation. The Journal of Physical Chemistry C, 126 (28), 11822-11832.	es_ES
dc.identifier.uri	https://hdl.handle.net/10550/87912
dc.description.abstract	A semiempirical model to describe the voltammetry of nontopotactic solid-to-solid redox processes occurring in the voltammetry of immobilized particles (VIMP) electrochemistry is described. It is applied to the reduction of solid metal compounds to the corresponding metal in contact with suitable electrolytes. The model is based on the assumption that the transferred charge is a logistic function of the applied potential, a situation that applies for reversible redox processes involving strongly adsorbed reactants. The model satisfactorily applies to reproduce linear potential scan curves recorded for graphite electrodes modified with different lead compounds (PbO, PbCl2·2H2O, lead-tin yellow, lead white) in contact with 0.10 M H2SO4 aqueous solution.	es_ES
dc.language.iso	en	es_ES
dc.publisher	ACS	es_ES
dc.subject	anode materials	es_ES
dc.subject	carbon	es_ES
dc.subject	charge transfer	es_ES
dc.subject	electrodes	es_ES
dc.subject	redox reactions	es_ES
dc.title	Description of Solid-to-Solid Redox Processes Based on the Voltammetry of Immobilized Particles Methodology: A Logistic Approximation	es_ES
dc.type	journal article	es_ES
dc.subject.unesco	UNESCO::CIENCIAS TECNOLÓGICAS	es_ES
dc.identifier.doi	10.1021/acs.jpcc.2c03041	es_ES
dc.accrualmethod	CI	es_ES
dc.embargo.terms	0 days	es_ES
dc.type.hasVersion	VoR	es_ES
dc.rights.accessRights	open access	es_ES