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A smartphone-based innovative approach to discriminate red pigments in roman frescoes mock-ups

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A smartphone-based innovative approach to discriminate red pigments in roman frescoes mock-ups

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dc.contributor.author Sáez Hernández, Roberto
dc.contributor.author Antela, Kevin U.
dc.contributor.author Gallello, Gianni
dc.contributor.author Cervera Sanz, Maria Luisa
dc.contributor.author Mauri Aucejo, Adela
dc.date.accessioned 2023-06-16T11:14:51Z
dc.date.available 2023-06-17T04:45:06Z
dc.date.issued 2022 es_ES
dc.identifier.citation Sáez-Hernández, R., Antela, K. U., Gallello, G., Cervera, M. L., & Mauri-Aucejo, A. R. (2022). A smartphone-based innovative approach to discriminate red pigments in roman frescoes mock-ups. Journal of Cultural Heritage, 58, 156-166. es_ES
dc.identifier.uri https://hdl.handle.net/10550/88333
dc.description.abstract The characterization of red pigments in frescoes wall paintings has been of great interest for researchers to better understand raw material procurement dynamics, pigment receipts, stylistic evolution and to assess their conservation state. In this study a non-destructive colorimetric approach implementing a smartphone-based method was developed in order to be able to distinguish between three pigments made from minium, haematite and cinnabar minerals, and also mixed pigments, preparing frescoes mock-ups following the roman receipt described by Vitruvius. Portable FT-IR, Raman spectroscopy, portable XRF and visible reflectance spectra analyses were carried out as reference methods for smartphone colorimetry results validation. Employing a reference colour sheet to control changing lighting conditions, different chemometric approaches have been developed and tested, cross-referencing standard analytical results with the data obtained by smartphone. Overall, using only colour parameters from the smartphone, a Linear Discriminant Analysis and a Support Vector Classifier were tested to efficiently classify each sample based on the red pigment used, with low prediction errors. This work shows the potential of smartphones as cheap, fast and user-friendly analytical devices for the screening of frescoes, and as a prior selective step before carrying out further more expensive and specialized analyses. es_ES
dc.language.iso en es_ES
dc.publisher Elsevier es_ES
dc.subject roman fresco es_ES
dc.subject smartphone es_ES
dc.subject spectroscopy es_ES
dc.subject mock-up es_ES
dc.subject pigment es_ES
dc.subject colorimetry es_ES
dc.title A smartphone-based innovative approach to discriminate red pigments in roman frescoes mock-ups es_ES
dc.type journal article es_ES
dc.subject.unesco UNESCO::CIENCIAS TECNOLÓGICAS es_ES
dc.identifier.doi 10.1016/j.culher.2022.10.003 es_ES
dc.accrualmethod CI es_ES
dc.embargo.terms 0 days es_ES
dc.type.hasVersion VoR es_ES
dc.rights.accessRights open access es_ES

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