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Distribution of Relaxation Times: Debye Length Distribution vsElectrode Polarization by a Cole−Cole Relaxation Model

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Distribution of Relaxation Times: Debye Length Distribution vsElectrode Polarization by a Cole−Cole Relaxation Model

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dc.contributor.author Compañ, Vicente
dc.contributor.author Diaz Calleja, Ricardo
dc.contributor.author Diaz Boils, Joaquín
dc.contributor.author Escorihuela, Jorge
dc.date.accessioned 2023-09-11T17:15:49Z
dc.date.available 2023-09-11T17:15:49Z
dc.date.issued 2022
dc.identifier.citation Compañ, Vicente Diaz Calleja, Ricardo Diaz Boils, Joaquín Escorihuela, Jorge 2022 Distribution of Relaxation Times: Debye Length Distribution vsElectrode Polarization by a Cole−Cole Relaxation Model Journal of the Electrochemical Society 169 1 013506
dc.identifier.uri https://hdl.handle.net/10550/89198
dc.description.abstract Mobility, diffusivity and charge density in polyelectrolytes, are generally determined from electrochemical impedance spectroscopy following the electrode polarization analysis, in which at a given temperature the peaks in tan δ are fitted based on a model. These results can be different depending on the model used in the fitting of the curves. Generally, the models are based on a single Debye model or on the existence of an overlap in relaxation times (Cole-Cole model). In this work, we propose the alternative use of the distribution of the relaxation times by a distribution of the Debye length (LD), which allows the calculation of parameters such as mobility, diffusivity, and charge density as a function of LD in a more concise approach.
dc.language.iso eng
dc.relation.ispartof Journal of the Electrochemical Society, 2022, vol. 169, num. 1, p. 013506
dc.subject Electrònica
dc.subject Electrònica Aparells i instruments
dc.title Distribution of Relaxation Times: Debye Length Distribution vsElectrode Polarization by a Cole−Cole Relaxation Model
dc.type journal article
dc.date.updated 2023-09-11T17:15:49Z
dc.identifier.doi 10.1149/1945-7111/ac4bf9
dc.identifier.idgrec 156451
dc.rights.accessRights open access

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