NAGIOS: RODERIC FUNCIONANDO

Metal Node Control of Brønsted Acidity in Heterobimetallic Titanium-Organic Frameworks

Repositori DSpace/Manakin

Valencià Castellano

Inici
Investigació
e-prints
23 - Química
Visualitza element

IMPORTANT: Aquest repositori està en una versió antiga des del 3/12/2023. La nova instal.lació está en https://roderic.uv.es/

Metal Node Control of Brønsted Acidity in Heterobimetallic Titanium-Organic Frameworks

Mostra el registre complet de l'element

Visualització (3.461Mb)

Rubio Gaspar, Ana; Navalón, Sergio; Tatay Aguilar, Sergio; Cirujano, Francisco G.; Fernández Conde, Carmen; Padial, Natalia M.; Martí Gastaldo, Carlos

Aquest document és un/a article, creat/da en: 2023

Compared to indirect framework modification, synthetic control of cluster composition can be used to gain direct access to catalytic activities exclusive of specific metal combinations. We demonstrate this concept by testing the aminolysis of epoxides with a family of isostructural mesoporous frameworks featuring five combinations of homometallic and heterobimetallic metal-oxo trimers (Fe3, Ti3, TiFe2, TiCo2, and TiNi2). Only TiFe2 nodes display activities comparable to benchmark catalysts based on grafting of strong acids, which here originate from the combination of Lewis Ti4+ and Brønsted Fe3+-OH acid sites. The applicability of MUV-101(Fe) to the synthesis of β-amino alcohols is demonstrated with a scope that also includes the gram scale synthesis of propranolol, a natural β-blocker listed as an essential medicine by the World Health Organization, with excellent yield and selectivity.

Veure al catàleg Trobes