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Synthesis of Known and Previously Inaccessible Poly(pyrazolyl)Borates under Mild Conditions
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Synthesis of Known and Previously Inaccessible Poly(pyrazolyl)Borates under Mild Conditions
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| dc.contributor.author | Melero, María M. | |
| dc.contributor.author | Klosek, Zuzanna | |
| dc.contributor.author | Ramírez de Arellano Sánchez, María del Carmen | |
| dc.contributor.author | Olmos Vergé, Andrea | |
| dc.date.accessioned | 2023-09-27T13:04:10Z | |
| dc.date.available | 2023-09-27T13:04:10Z | |
| dc.date.issued | 2023 | |
| dc.identifier.citation | Melero, María M. Klosek, Zuzanna Ramírez de Arellano Sánchez, María del Carmen Olmos Vergé, Andrea 2023 Synthesis of Known and Previously Inaccessible Poly(pyrazolyl)Borates under Mild Conditions Journal of Organic Chemistry 88 13 9130 9135 | |
| dc.identifier.uri | https://hdl.handle.net/10550/89667 | |
| dc.description.abstract | Poly(pyrazolyl)borate ligands have been obtained through the reaction of highly reactive haloboranes with in situ formed pyrazolides under very mild conditions. This versatile synthetic method allows the selective synthesis of bis-, tris-, or tetrakis(pyrazolyl)borates. Furthermore, the method is compatible with the use of functional groups on the heterocyclic moieties of the poly(pyrazolyl)- borates that were not accessible to date. Strongly encumbered sodium and thallium(I) poly(pyrazolyl)borates with a reduced donating ability have been obtained for the first time. | |
| dc.language.iso | eng | |
| dc.relation.ispartof | Journal of Organic Chemistry, 2023, vol. 88, num. 13, p. 9130-9135 | |
| dc.subject | Química orgànica | |
| dc.title | Synthesis of Known and Previously Inaccessible Poly(pyrazolyl)Borates under Mild Conditions | |
| dc.type | journal article | |
| dc.date.updated | 2023-09-27T13:04:10Z | |
| dc.identifier.doi | 10.1021/acs.joc.3c00761 | |
| dc.identifier.idgrec | 161326 | |
| dc.rights.accessRights | open access |
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