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Tunable Supramolecular Ag+-Host Interactions in Pillar[n]arene[m]quinones and Ensuing Specific Binding to 1-Alkynes

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Tunable Supramolecular Ag+-Host Interactions in Pillar[n]arene[m]quinones and Ensuing Specific Binding to 1-Alkynes

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dc.contributor.author	Zhu, Yumei
dc.contributor.author	Escorihuela Fuentes, Jorge
dc.contributor.author	Wang, Haiying
dc.contributor.author	Sue, Andrew C.-H.
dc.contributor.author	Zuilhof, Han
dc.date.accessioned	2023-11-15T14:28:25Z
dc.date.available	2023-11-15T14:28:25Z
dc.date.issued	2023
dc.identifier.uri	https://hdl.handle.net/10550/91187
dc.description.abstract	We developed an improved, robust synthesis of a series of pillar[6]arenes with a varying number (0-3) of quinone moieties in the ring. This easy-to-control variation yielded a gradually less electron-rich cavity in going from zero to three quinone units, as shown from the strength of host-guest interactions with silver ions. Such macrocycle-Ag2 complexes themselves were shown to display an unprecedented, sharp distinction between terminal alkynes, which strongly bound to such complexes, and internal alkynes, internal alkenes and terminal alkenes, which do hardly bind.
dc.language.iso	eng
dc.relation.ispartof	Molecules, 2023, vol. 28, num. 20, p. 7009
dc.source	Zhu, Yumei Escorihuela Fuentes, Jorge Wang, Haiying Sue, Andrew C.-H. Zuilhof, Han 2023 Tunable Supramolecular Ag+-Host Interactions in Pillar[n]arene[m]quinones and Ensuing Specific Binding to 1-Alkynes Molecules 28 20 7009
dc.subject	Química orgànica
dc.title	Tunable Supramolecular Ag+-Host Interactions in Pillar[n]arene[m]quinones and Ensuing Specific Binding to 1-Alkynes
dc.type	journal article
dc.date.updated	2023-11-15T14:28:25Z
dc.identifier.doi	10.3390/molecules28207009
dc.identifier.idgrec	161848
dc.rights.accessRights	open access