NAGIOS: RODERIC FUNCIONANDO

Synthesis and application of new iminopyridine ligands in the enantioselective palladium-catalyzed allylic alkylation

Repositori DSpace/Manakin

Valencià Castellano

Inici
Investigació
e-prints
23 - Química
Visualitza element

IMPORTANT: Aquest repositori està en una versió antiga des del 3/12/2023. La nova instal.lació está en https://roderic.uv.es/

Synthesis and application of new iminopyridine ligands in the enantioselective palladium-catalyzed allylic alkylation

Mostra el registre parcial de l'element

dc.contributor.author	Solinas, Maurizio
dc.contributor.author	Sechi, Barbara
dc.contributor.author	Chelucci, Giorgio
dc.contributor.author	Baldino, Salvatore
dc.contributor.author	Pedro, José Ramón
dc.contributor.author	Blay Llinares, Gonzalo
dc.date.accessioned	2014-02-26T09:11:17Z
dc.date.available	2014-02-26T09:11:17Z
dc.date.issued	2014
dc.identifier.citation	Solinas, Maurizio Sechi, Barbara Chelucci, Giorgio Baldino, Salvatore Pedro, José Ramón Blay Llinares, Gonzalo 2014 Synthesis and application of new iminopyridine ligands in the enantioselective palladium-catalyzed allylic alkylation Journal of Molecular Catalysis A-Chemical 385 73 77
dc.identifier.uri	http://hdl.handle.net/10550/33330
dc.description.abstract	A variety of iminopyridines were obtained by condensation of chiral amines with pyridine-2-carboxaldehyde and quinoline-8-carbaldehyde, or of aminoalkylpyridine derivatives with chiral ketones. These ligands were assessed in the enantioselective palladium catalyzed allylic substitutionof 1,3-diphenylprop-2-enyl acetate with dimethyl malonate affording the product dimethyl 1,3-diphenylprop-2-enylmalonate in good yields and moderate enantioselectivities (up to 62% ee). Catalytic activity and enantioselectivity were found to be highly dependent upon the steric properties of the ligands. The best enantioselectivity (62% ee) was obtained by an iminopyridine based on a camphane skeleton.
dc.relation.ispartof	Journal of Molecular Catalysis A-Chemical, 2014, vol. 385, p. 73-77
dc.subject	Química
dc.title	Synthesis and application of new iminopyridine ligands in the enantioselective palladium-catalyzed allylic alkylation
dc.type	journal article	es_ES
dc.date.updated	2014-02-26T09:11:17Z
dc.identifier.doi	10.1016/j.molcata.2014.01.006
dc.identifier.idgrec	093689
dc.rights.accessRights	open access	es_ES
dc.identifier.url	10.1016/j.molcata.2014.01.006