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Direct visualization of pyrrole reactivity by confined oxidation in a Cyclodextrin Metal‐Organic Framework

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Direct visualization of pyrrole reactivity by confined oxidation in a Cyclodextrin Metal‐Organic Framework

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dc.contributor.author	Núñez-López, Alejandro
dc.contributor.author	Galbiati, Marta
dc.contributor.author	Padial, Natalia M.
dc.contributor.author	Ganivet, Carolina R.
dc.contributor.author	Tatay Aguilar, Sergio
dc.contributor.author	Pardo Marín, Emilio
dc.contributor.author	Armentano, Donatella
dc.contributor.author	Martí Gastaldo, Carlos
dc.date.accessioned	2019-07-08T12:58:28Z
dc.date.available	2019-07-10T04:45:05Z
dc.date.issued	2019
dc.identifier.citation	Núñez-López, Alejandro Galbiati, Marta Padial, Natalia M. Ganivet, Carolina R. Tatay Aguilar, Sergio Pardo Marín, Emilio Armentano, Donatella Martí Gastaldo, Carlos 2019 Direct visualization of pyrrole reactivity by confined oxidation in a Cyclodextrin Metal‐Organic Framework Angewandte Chemie 58 27 9179 9183
dc.identifier.uri	https://hdl.handle.net/10550/70758
dc.description.abstract	Metal-organic frameworks can be used as porous templates to exert control over polymerization reactions. Shown here are the possibilities offered by these crystalline, porous nanoreactors to capture highly‐reactive intermediates for a better understanding of the mechanism of polymerization reactions. By using a cyclodextrin framework the polymerization of pyrrole is restricted, capturing the formation of terpyrrole cationic intermediates. Single‐crystal X‐ray diffraction is used to provide definite information on the supramolecular interactions that induce the formation and stabilization of a conductive array of cationic complexes.
dc.language.iso	eng
dc.relation.ispartof	Angewandte Chemie, 2019, vol. 58, num. 27, p. 9179-9183
dc.subject	Química organometàl·lica
dc.subject	Reactivitat (Química)
dc.title	Direct visualization of pyrrole reactivity by confined oxidation in a Cyclodextrin Metal‐Organic Framework
dc.type	journal article	es_ES
dc.date.updated	2019-07-08T12:58:28Z
dc.identifier.doi	10.1002/anie.201904890
dc.identifier.idgrec	133389
dc.embargo.terms	1 year
dc.rights.accessRights	open access	es_ES