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Molecular Iodine for a General Synthesis of Binary and Ternary Inorganic and Hybrid Organic-inorganic Iodide Nanocrystals

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Molecular Iodine for a General Synthesis of Binary and Ternary Inorganic and Hybrid Organic-inorganic Iodide Nanocrystals

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dc.contributor.author Akkerman, Quinten A.
dc.contributor.author Martínez Sarti, Laura
dc.contributor.author Goldoni, Luca
dc.contributor.author Imran, Muhammad
dc.contributor.author Baranov, Dmitry
dc.contributor.author Bolink, Henk
dc.contributor.author Palazón Huet, Francisco
dc.contributor.author Manna, Liberato
dc.date.accessioned 2020-06-18T08:39:51Z
dc.date.available 2020-06-18T08:39:51Z
dc.date.issued 2018
dc.identifier.citation Akkerman, Quinten A. Martínez Sarti, Laura Goldoni, Luca Imran, Muhammad Baranov, Dmitry Bolink, Henk Palazón Huet, Francisco Manna, Liberato 2018 Molecular Iodine for a General Synthesis of Binary and Ternary Inorganic and Hybrid Organic-inorganic Iodide Nanocrystals Chemistry of Materials 30 6915 6921
dc.identifier.uri https://hdl.handle.net/10550/75111
dc.description.abstract We report the synthesis of various binary and ternary inorganic and hybrid organic-inorganic iodide nanocrystals starting from molecular iodine (I2). The procedure utilizes a reaction between I2 and oleylamine that yields oleylammonium iodide -the iodide precursor for a subsequent preparation of nanocrystals. The syntheses are facile, carried out under air, in vials heated on a hotplate and deliver nanocrystals with narrow size distributions and, in the case of red and near infrared-emitting lead-based perovskites, with 70-80% photoluminescence quantum yields. The latter were used to fabricate red and infrared bright light-emitting diodes, with external quantum efficiencies (EQE) exceeding 3%.
dc.language.iso eng
dc.relation.ispartof Chemistry of Materials, 2018, vol. 30, p. 6915-6921
dc.subject Materials
dc.subject Nanotecnologia
dc.title Molecular Iodine for a General Synthesis of Binary and Ternary Inorganic and Hybrid Organic-inorganic Iodide Nanocrystals
dc.type journal article es_ES
dc.date.updated 2020-06-18T08:39:51Z
dc.identifier.doi 10.1021/acs.chemmater.8b03295
dc.identifier.idgrec 127005
dc.rights.accessRights open access es_ES

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