Magnesium Exchanged Zirconium Metal−Organic Frameworks with Improved Detoxification Properties of Nerve Agents
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Gil-San-Millan, Rodrigo; López Maya, Elena; ́Platero-Prats, Ana E.; Torres-Pérez, Virginia; Delgado, Pedro; ́Augustyniak, Adam W.; Kim, Min Kun; Lee, Hae Wan; Ryu, Sam Gon; Navarro, Jorge A. R.
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Aquest document és un/a article, creat/da en: 2019
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UiO-66, MOF-808 and NU-1000 metal-organic frameworks exhibit a differentiated reactivity toward [Mg(OMe)2(MeOH)2]4 related to their pore accessibility. Microporous UiO-66 remains unchanged while mesoporous MOF-808 and hierarchical micro/mesoporous NU-1000 materials yield doped systems containing exposed MgZr5O2(OH)6 clusters in the mesoporous cavities. This modification is responsible for a remarkable enhancement of the catalytic activity toward the hydrolytic degradation of P-F and P-S bonds of toxic nerve agents, at room temperature, in unbuffered aqueous solutions. |
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