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Influence of interpenetration on the flexibility of MUV-2
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Influence of interpenetration on the flexibility of MUV-2
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| Vicent-Morales, María; Vitórica-Yrezábal, Iñigo J.; Souto, Manuel; Mínguez Espallargas, Guillermo | |||
| Aquest document és un/a article, creat/da en: 2019 | |||
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| The crystal structure of an interpenetrated tetrathiafulvalene (TTF)-based metal-organic framework (MOF) is reported. This MOF, denoted as MUV-2-i, is the interpenetrated analogue of the hierarchical and flexible MUV-2. Interestingly, the large flexibility exhibited by MUV-2 upon polar solvent adsorption is considerably reduced in the interpenetrated form which can be explained by short S⋯S interactions between adjacent TTF-based ligands ensuring more rigidity in the framework. In addition, the porosity of MUV-2-i is significantly decreased in comparison to that of MUV-2 as shown by the reduced free volume in the crystal structure. | |||
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23 - Química [1060]