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Influence of interpenetration on the flexibility of MUV-2

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Influence of interpenetration on the flexibility of MUV-2

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dc.contributor.author	Vicent-Morales, María
dc.contributor.author	Vitórica-Yrezábal, Iñigo J.
dc.contributor.author	Souto, Manuel
dc.contributor.author	Mínguez Espallargas, Guillermo
dc.date.accessioned	2021-07-14T12:42:15Z
dc.date.available	2021-07-14T12:42:15Z
dc.date.issued	2019
dc.identifier.citation	Vicent-Morales, María Vitórica-Yrezábal, Iñigo J. Souto, Manuel Mínguez Espallargas, Guillermo 2019 Influence of interpenetration on the flexibility of MUV-2 Crystengcomm 21 3031 3035
dc.identifier.uri	https://hdl.handle.net/10550/79930
dc.description.abstract	The crystal structure of an interpenetrated tetrathiafulvalene (TTF)-based metal-organic framework (MOF) is reported. This MOF, denoted as MUV-2-i, is the interpenetrated analogue of the hierarchical and flexible MUV-2. Interestingly, the large flexibility exhibited by MUV-2 upon polar solvent adsorption is considerably reduced in the interpenetrated form which can be explained by short S⋯S interactions between adjacent TTF-based ligands ensuring more rigidity in the framework. In addition, the porosity of MUV-2-i is significantly decreased in comparison to that of MUV-2 as shown by the reduced free volume in the crystal structure.
dc.language.iso	eng
dc.relation.ispartof	Crystengcomm, 2019, vol. 21, p. 3031-3035
dc.subject	Cristalls
dc.subject	Materials
dc.title	Influence of interpenetration on the flexibility of MUV-2
dc.type	journal article	es_ES
dc.date.updated	2021-07-14T12:42:15Z
dc.identifier.doi	10.1039/C9CE00233B
dc.identifier.idgrec	134268
dc.rights.accessRights	open access	es_ES