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Imparting structural robustness of metal-organic cages based on oxo-dimolybdenum clusters

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Valencià Castellano

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Imparting structural robustness of metal-organic cages based on oxo-dimolybdenum clusters

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Delaporte, Solène; Abánades Lázaro, Isabel; López Cabrelles, Javier; Mazarakioti, Eleni C.; Chebourou, Sarah; Giménez-Marqués, Mónica; Mínguez Espallargas, Guillermo

Aquest document és un/a article, creat/da en: 2023

A family of robust and stable molybdenum-based metal-organic cages have been obtained based on the [Mo2O2(μ2-O)2]2+ secondary building unit. The resulting cages are decorated with different pyrdine derivatives that impart structural stability, resulting in the structural elucidation of the activated cage with single-crystal diffraction. The chemical robustness of the cage is also demonstrated by the post-synthetic modification of the cage, which allows the exchange of the pyridine derivatives without rupture of the cage.

Delaporte, Solène, Abánades Lázaro, Isabel, López Cabrelles, Javier, Mazarakioti, Eleni C., Chebourou, Sarah ,Giménez-Marqués, Mónica, Mínguez Espallargas, Guillermo (2023). Imparting structural robustness of metal-organic cages based on oxo-dimolybdenum clusters. Dalton Transactions 52 15682 15687. https://doi.org/10.1039/D3DT02482B